One more comment to what Dean said. If you right-click on "My Documents" and
select properties, you will have an option to move your "My Documents"
folder to another location. This is where you may chose to move it to your
new drive. If Dean is correct about where iTunes stores its info, then
moving "My Documents" will solve your iTunes problem.

Peter
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-----Original Message-----
I would like to add my two cent's worth to what Peter said.

It has been a while since I installed iTunes, but I believe that when you
install it, it asks for the name of the folder where your music will be
kept.  It likely suggests the "default" value of MyMusic on the C: drive. 
On my somewhat older version of iTunes if you go to
Edit/Preferences/Advanced, you will see the name of the folder where your
music is kept, and you can change that name to that of a folder on your new
hard drive.  Then, when you download or rip stuff using iTunes, you send it
to that new folder with much greater capacity.

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