You probably aren't selecting the IJ600 as your default printer or as the 
printer of choice from the drop-down menu located in the "file" "print" 
command.

Next time you print from Word, don't click on the printer icon, click on 
"File" and drag down to "print." At the first screen, take note of what 
printer it has selected for you to print to. You can change that selection 
by clicking on the down arrow to the right of the printer's name and you 
will likely see your IJ600 as one of the selections for which you may 
choose.

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The printer will do a test page on every connect but can't print a WORD doc

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